Bas de Bruin
Professor of Homogeneous of catalysis
University of Amsterdam
About me
I expect that the ARC-CBBC enables me to work on challenging topics, relevant for science & society, in direct collaboration with industry and yet of fundamental interest. Applied research combined with fundamental challenges. The best of both worlds. Existing contacts with partners at AkzoNobel and Shell already led us to to define several interesting and challenging topics to work on. I look forward to start!About my research
I am proud of having developed several new catalytic reactions, and having provided mechanistic insights of several homogeneously catalyzed reactions that allowed us to develop such new reactions. As such we contribute to science and society. I am also proud of being elected a member of the ARC-CBBC. Furthermore, I am of course proud of the publications we published in high impact journals like Science, JACS, Angewandte Chemie, etc. But most of all I am proud of all my hardworking, kind and devoted undergraduate students, PhD students and postdocs.Academic career
Publications
Light Induced Cobalt(III) Carbene Radical Formation from Dimethyl Malonate As Carbene Precursor
D. Snabilié, R. Ham, J. Reek, B. de Bruin
Atom Transfer Radical Addition of Activated Primary Alkyl Chlorides Using In Situ Generated [Cp*RuII(Cl)(PR3)] Catalysts
N.S. van Leeuwen, S. Mathew, C.E.J. van Lare, M.P. Ahr, A. Zwijnenburg, S. Pullen, B. de Bruin
Thermal/Blue Light Induced Cross-Linking of Acrylic Coatings with Diazo Compounds
F.J. de Zwart, L.A. Wolzak, P.C.M. Laan, S. Mathew, J. Flapper, K.J. van den Berg, J.N.H. Reek, and B. de Bruin
Carbene Radicals in Transition-Metal-Catalyzed Reactions
R.F.J. Epping, D. Vesseur, M. Zhou, and B. de Bruin
Understanding Off-Cycle and Deactivation Pathways in Radical-Type Carbene Transfer Catalysis
D.D. Snabilié, E.J. Meeus, R.F.J. Epping, Z. He, M. Zhou, and B. de Bruin
Isocyanate-Free Polyurea Synthesis via Ru-Catalyzed Carbene Insertion into the N–H Bonds of Urea
F.J. de Zwart, P.C.M. Laan, N.S. van Leeuwen, E.O. Bobylev, E.R. Amstalden van Hove, S. Mathew, N. Yan, J. Flapper, K.J. van den Berg, J.N.H. Reek, and B. de Bruin
Thermal and (Thermo-Reversible) Photochemical Cycloisomerization of 1H-2-Benzo[c]oxocins: From Synthetic Applications to the Development of a New T-Type Molecular Photoswitch
M. Zhou, S. Mathew, and B. de Bruin
Exogenous Ligand-Free Nickel-Catalyzed Carboxylate O-Arylation: Insight into NiI/NiIII Cycles
L.A. Wolzak, F.J. de Zwart, J.P.H. Oudsen, S.A. Bartlett, B. de Bruin, J.N.H. Reek, M. Tromp, T.J. Korstanje
Reactivity of a Unique Si(I)–Si(I)-Based η2-Bis(silylene) Iron Complex
Z. He, L. Liu, F.J. de Zwart, X. Xue, A.W. Ehlers, K. Yan, S. Demeshko, J.I. van der Vlugt, B. de Bruin, and J. Krogman
Photoactive Fe Catalyst for Light-Triggered Alkyd Paint Curing
J. Bootsma, W.R. Browne, J. Flapper, and B. de Bruin
Computational mechanistic studies of ruthenium catalysed methanol dehydrogenation
F. J. de Zwart, V. Sinha, M. Trincado, H. Grützmacher, B. de Bruin
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